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Physical organic chemistry Homework Help

 

Physical organic chemistry Homework Help :

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Physical organic chemistry is the study of the interrelationships between structure and reactivity in organic molecules. It can be seen as the study of organic chemistry using tools of physical chemistry such as chemical equilibrium, chemical kinetics, thermochemistry, and quantum chemistry. The term "physical organic chemistry" is commonly attributed to Louis Hammett, who used it as a title for a book in 1940.

The two main themes in physical organic chemistry are structure and reactivity. The study of structure starts from chemical bonding, with special emphasis on the stability of organic molecules due to factors such as steric strain and aromaticity.

Other topics in structure include stereochemistry and conformational analysis. Supramolecular structure is also considered in terms of intermolecular forces including hydrogen bonding. Finally, the acid-base chemistry of the molecules is studied in terms of structure, based on resonance and inductive effects and through the use of linear free-energy relations.

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